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Issue 38, 2009
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Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters

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Abstract

Pd(II)- and Pt(II)-catalyzed ring-expansion of enantiomerically pure alkylidenecyclopropane derivatives leads to the formation of cyclobutene species with a complete preservation of the stereogenic center.

Graphical abstract: Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters

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Article information


Submitted
28 May 2009
Accepted
07 Aug 2009
First published
02 Sep 2009

Chem. Commun., 2009, 5760-5762
Article type
Communication

Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters

A. Masarwa, A. Fürstner and I. Marek, Chem. Commun., 2009, 5760
DOI: 10.1039/B910465H

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