Inclusion of C60 into the hexagonal columnar space formed by intra- and intermolecular CH⋯π interactions

Junji Kobayashi; Yuya Domoto; Takayuki Kawashima

doi:10.1039/B909881J

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Inclusion of C₆₀ into the hexagonal columnar space formed by intra- and intermolecular CH⋯π interactions†

Junji Kobayashi,*^a Yuya Domoto^a and Takayuki Kawashima*^a

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* Corresponding authors

^a Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
E-mail: jkoba@chem.s.u-tokyo.ac.jp, takayuki@chem.s.u-tokyo.ac.jp
Fax: +81-3-5800-6899
Tel: +81-3-5841-4338

Abstract

A triarylmethane-based host molecule with three anthryl groups that can interact with C₆₀ was synthesized. Co-recrystallization of this host molecule with C₆₀ resulted in a linear alignment of C₆₀ in the hexagonal columnar space formed by intra- and intermolecular CH⋯π interactions between anthryl groups in the crystalline state.

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Article information

DOI: https://doi.org/10.1039/B909881J
Article type: Communication
Submitted: 19 May 2009
Accepted: 07 Sep 2009
First published: 17 Sep 2009

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Chem. Commun., 2009, 6186-6188

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Inclusion of C₆₀ into the hexagonal columnar space formed by intra- and intermolecular CH⋯π interactions

J. Kobayashi, Y. Domoto and T. Kawashima, Chem. Commun., 2009, 6186 DOI: 10.1039/B909881J

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