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Issue 37, 2009
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Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2,2′:6′,2″-terpyridine

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Abstract

Thermal activation of terpyridine in the presence of an unsaturated Ir(III) fragment stabilized by a hydrotris(pyrazolyl) borate ligand gives rise to mononuclear complex 2 and binuclear 3, in which the polypyridine behaves, respectively, as a mono- or a bi-dentate N-heterocyclic carbene.

Graphical abstract: Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2,2′:6′,2″-terpyridine

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Publication details

The article was received on 18 May 2009, accepted on 03 Aug 2009 and first published on 18 Aug 2009


Article type: Communication
DOI: 10.1039/B909837B
Chem. Commun., 2009, 5561-5563

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    Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2,2′:6′,2″-terpyridine

    M. Paneque, M. L. Poveda, F. Vattier, E. Alvarez and E. Carmona, Chem. Commun., 2009, 5561
    DOI: 10.1039/B909837B

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