Issue 27, 2009

Gold-catalyzed oxidative cleavage of aryl-substituted alkynyl ethers using molecular oxygen. Simultaneous degradation of C–H and single and triple carbon–carbon bonds under ambient conditions

Abstract

We report the gold-catalyzed oxidative cleavage of aryl-substituted alkynyl ethers using molecular oxygen under ambient conditions; the transformation involves a remarkable cleavage of C–H, C–C and C[triple bond, length as m-dash]C bonds simultaneously.

Graphical abstract: Gold-catalyzed oxidative cleavage of aryl-substituted alkynyl ethers using molecular oxygen. Simultaneous degradation of C–H and single and triple carbon–carbon bonds under ambient conditions

Supplementary files

Article information

Article type
Communication
Submitted
27 Apr 2009
Accepted
01 Jun 2009
First published
10 Jun 2009

Chem. Commun., 2009, 4046-4048

Gold-catalyzed oxidative cleavage of aryl-substituted alkynyl ethers using molecular oxygen. Simultaneous degradation of C–H and single and triple carbon–carbon bonds under ambient conditions

A. Das, R. Chaudhuri and R. Liu, Chem. Commun., 2009, 4046 DOI: 10.1039/B908338C

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