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Issue 29, 2009
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Use of 4-piperidones in one-pot syntheses of novel, high-molecular-weight linear and virtually 100%-hyperbranched polymers

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Abstract

4-Piperidone and 4-alkyl piperidones react selectively with aromatic hydrocarbons in a mixture of trifluoromethanesulfonic acid (TFSA) and CH2Cl2 to give linear polymers, while N-(2-phenethyl)piperidone undergoes self-polymerization to yield virtually 100%-hyperbranched polymer.

Graphical abstract: Use of 4-piperidones in one-pot syntheses of novel, high-molecular-weight linear and virtually 100%-hyperbranched polymers

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Article information


Submitted
07 Apr 2009
Accepted
19 May 2009
First published
10 Jun 2009

Chem. Commun., 2009, 4408-4410
Article type
Communication

Use of 4-piperidones in one-pot syntheses of novel, high-molecular-weight linear and virtually 100%-hyperbranched polymers

A. R. Cruz, M. G. Zolotukhin, S. L. Morales, J. Cardenas, G. Cedillo, S. Fomine, M. Salmon and M. P. Carreón-Castro, Chem. Commun., 2009, 4408
DOI: 10.1039/B907042G

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