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Issue 30, 2009
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Dihydrogen complexes: striking effect of ion pairing to BF4 on the rotation of coordinated dihydrogen and the 19F relaxation time

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Abstract

Unexpected changes in the T1 values for the 19F NMR signal of the BF4 anion in the presence of dihydrogen complexes reveal that ion pairing with BF4⋯H2 interactions of different strengths can lead to significant changes in the rotation barrier for coordinated dihydrogen.

Graphical abstract: Dihydrogen complexes: striking effect of ion pairing to BF4− on the rotation of coordinated dihydrogen and the 19F relaxation time

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Publication details

The article was received on 31 Mar 2009, accepted on 04 Jun 2009 and first published on 22 Jun 2009


Article type: Communication
DOI: 10.1039/B906330G
Chem. Commun., 2009, 4563-4565

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    Dihydrogen complexes: striking effect of ion pairing to BF4 on the rotation of coordinated dihydrogen and the 19F relaxation time

    A. G. Algarra, M. J. Fernández-Trujillo, A. Lledós and M. G. Basallote, Chem. Commun., 2009, 4563
    DOI: 10.1039/B906330G

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