Issue 28, 2009

Sulfur-tagged metal–organic frameworks and their post-synthetic oxidation

Abstract

A series of sulfur-tagged zinc MOFs containing functionalised 4,4′-biphenyldicarboxylate ligands has been prepared: oxidative post-synthetic modification with dimethyldioxirane has converted the sulfide tags into sulfones, leaving the MOF networks intact.

Graphical abstract: Sulfur-tagged metal–organic frameworks and their post-synthetic oxidation

Supplementary files

Article information

Article type
Communication
Submitted
27 Mar 2009
Accepted
26 May 2009
First published
08 Jun 2009

Chem. Commun., 2009, 4218-4220

Sulfur-tagged metal–organic frameworks and their post-synthetic oxidation

A. D. Burrows, C. G. Frost, M. F. Mahon and C. Richardson, Chem. Commun., 2009, 4218 DOI: 10.1039/B906170C

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