Issue 22, 2009

Asymmetric Friedel–Crafts reaction of N-heterocycles and nitroalkenes catalyzed by imidazoline–aminophenol–Cu complex

Abstract

Catalytic asymmetric Friedel–Crafts reaction of pyrrole with nitroalkenes was smoothly catalyzed by newly synthesized nitro-substituted imidazolineaminophenol (1b)–Cu complex to give the adduct with up to 92% ee.

Graphical abstract: Asymmetric Friedel–Crafts reaction of N-heterocycles and nitroalkenes catalyzed by imidazoline–aminophenol–Cu complex

Supplementary files

Article information

Article type
Communication
Submitted
02 Mar 2009
Accepted
02 Apr 2009
First published
24 Apr 2009

Chem. Commun., 2009, 3285-3287

Asymmetric Friedel–Crafts reaction of N-heterocycles and nitroalkenes catalyzed by imidazolineaminophenol–Cu complex

N. Yokoyama and T. Arai, Chem. Commun., 2009, 3285 DOI: 10.1039/B904275J

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