Issue 20, 2009

Ag(i)-mediated formation of pyrophosphonate coupled with C–C bond cleavage of acetonitrile

Abstract

A general approach to obtain pyrophosphonates is achieved by reacting arylphosphonic acids with AgNO3 in CH3CN under solvothermal conditions; the process is coupled with the C–C bond cleavage of acetonitrile and the formation of novel complexes [Agn(RPO2(O)O2PR)m](CN); the mechanism of the process is proposed.

Graphical abstract: Ag(i)-mediated formation of pyrophosphonate coupled with C–C bond cleavage of acetonitrile

Supplementary files

Article information

Article type
Communication
Submitted
02 Feb 2009
Accepted
16 Mar 2009
First published
06 Apr 2009

Chem. Commun., 2009, 2893-2895

Ag(I)-mediated formation of pyrophosphonate coupled with C–C bond cleavage of acetonitrile

L. Guo, S. Bao, Y. Li and L. Zheng, Chem. Commun., 2009, 2893 DOI: 10.1039/B902162K

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