Azide        groups in high oxidation state Mn carboxylate chemistry: a new Mn11 complex and its conversion to a Mn25 azide complex with Me3SiN3

Theocharis C. Stamatatos; Alina Vinslava; Khalil A. Abboud; George Christou

doi:10.1039/B902016K

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Azide groups in high oxidation state Mn carboxylate chemistry: a new Mn₁₁ complex and its conversion to a Mn₂₅azide complex with Me₃SiN₃†

Theocharis C. Stamatatos,^a Alina Vinslava,^a Khalil A. Abboud^a and George Christou*^a

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* Corresponding authors

^a Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, USA
E-mail: christou@chem.ufl.edu
Fax: +1-352-392-6737
Tel: +1-352-392-8314

Abstract

A new high oxidation state Mn^III^/IV₁₁carboxylate complex has been prepared and then converted to a Mn^II^/III₂₅ azide/carboxylate cluster with Me₃SiN₃; the Mn₂₅ product is the initial example of a higher oxidation state Mn azide complex not stabilized by any chelate ligands.

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Article information

DOI: https://doi.org/10.1039/B902016K
Article type: Communication
Submitted: 30 Jan 2009
Accepted: 24 Mar 2009
First published: 22 Apr 2009

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Chem. Commun., 2009, 2839-2841

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Azide groups in high oxidation state Mn carboxylate chemistry: a new Mn₁₁ complex and its conversion to a Mn₂₅ azide complex with Me₃SiN₃

T. C. Stamatatos, A. Vinslava, K. A. Abboud and G. Christou, Chem. Commun., 2009, 2839 DOI: 10.1039/B902016K

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