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Issue 16, 2009
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Unexpected nucleophilic behaviour of free-radicals generated from α-iodoketones

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Abstract

The unexpected nucleophilic reactivity of free-radicals generated from α-iodoketones is reported; two different procedures, either employing tin or the more environmentally acceptable ethylsulfone-based coupling reagent 5c have been developed.

Graphical abstract: Unexpected nucleophilic behaviour of free-radicals generated from α-iodoketones

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Publication details

The article was received on 29 Jan 2009, accepted on 05 Mar 2009 and first published on 19 Mar 2009


Article type: Communication
DOI: 10.1039/B901943J
Chem. Commun., 2009, 2142-2144

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    Unexpected nucleophilic behaviour of free-radicals generated from α-iodoketones

    C. De Dobbeleer, J. Pospíšil, F. De Vleeschouwer, F. De Proft and I. E. Markó, Chem. Commun., 2009, 2142
    DOI: 10.1039/B901943J

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