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Issue 21, 2009
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Asymmetric tandem Michael addition–ylide olefination reaction for the synthesis of optically active cyclohexa-1,3-diene derivatives

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Abstract

The reaction of a crotonate-derived chiral phosphonium salt with α,β-unsaturated carbonyl compounds in the presence of Cs2CO3 affords optically active cyclohexa-1,3-diene derivatives with up to 90% ee in good yields.

Graphical abstract: Asymmetric tandem Michael addition–ylide olefination reaction for the synthesis of optically active cyclohexa-1,3-diene derivatives

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Article information


Submitted
05 Jan 2009
Accepted
24 Mar 2009
First published
15 Apr 2009

Chem. Commun., 2009, 3092-3094
Article type
Communication

Asymmetric tandem Michael additionylide olefination reaction for the synthesis of optically active cyclohexa-1,3-diene derivatives

L. Ye, S. Wang, Q. Wang, X. Sun, Y. Tang and Y. Zhou, Chem. Commun., 2009, 3092
DOI: 10.1039/B900048H

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