A novel type of heteropolyoxoanion precursors {[Ca(H2O)]6[P4M6O34]2}12− (M = WVI, MoVI) constructed by two [P4M6O34]12− subunits via a rare hexa-calcium cluster

Jingping Wang; Junwei Zhao; Pengtao Ma; Junchuang Ma; Linping Yang; Yan Bai; Mingxue Li; Jingyang Niu

doi:10.1039/B822368H

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A novel type of heteropolyoxoanion precursors {[Ca(H₂O)]₆[P₄M₆O₃₄]₂}¹²⁻ (M = W^VI, Mo^VI) constructed by two [P₄M₆O₃₄]¹²⁻ subunits via a rare hexa-calcium cluster†

Jingping Wang,^a Junwei Zhao,^a Pengtao Ma,^a Junchuang Ma,^a Linping Yang,^a Yan Bai,^a Mingxue Li^a and Jingyang Niu*^a

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* Corresponding authors

^a Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, PR China
E-mail: jyniu@henu.edu.cn
Fax: (+86) 378 3886876

Abstract

A novel type of heteropolyoxoanion (HPOA) precursors {[Ca (H₂O)]₆[P₄M₆O₃₄]₂}¹²⁻ [M = W^VI (1), Mo^VI (2)] has been synthesized and structurally characterized, which represents the rare membership of the HPOA family constituted by two early-transition-metal clusters ([P₄M₆O₃₄]¹²⁻) and a main-group metal cluster of high nuclearity ([Ca₆]¹²⁺).

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Article information

DOI: https://doi.org/10.1039/B822368H
Article type: Communication
Submitted: 12 Dec 2008
Accepted: 11 Mar 2009
First published: 27 Mar 2009

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Chem. Commun., 2009, 2362-2364

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A novel type of heteropolyoxoanion precursors {[Ca(H₂O)]₆[P₄M₆O₃₄]₂}¹²⁻ (M = W^VI, Mo^VI) constructed by two [P₄M₆O₃₄]¹²⁻ subunits via a rare hexa-calcium cluster

J. Wang, J. Zhao, P. Ma, J. Ma, L. Yang, Y. Bai, M. Li and J. Niu, Chem. Commun., 2009, 2362 DOI: 10.1039/B822368H

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Chemical Communications