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Issue 17, 2009
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A novel type of heteropolyoxoanion precursors {[Ca(H2O)]6[P4M6O34]2}12− (M = WVI, MoVI) constructed by two [P4M6O34]12− subunits via a rare hexa-calcium cluster

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Abstract

A novel type of heteropolyoxoanion (HPOA) precursors {[Ca (H2O)]6[P4M6O34]2}12− [M = WVI (1), MoVI (2)] has been synthesized and structurally characterized, which represents the rare membership of the HPOA family constituted by two early-transition-metal clusters ([P4M6O34]12−) and a main-group metal cluster of high nuclearity ([Ca6]12+).

Graphical abstract: A novel type of heteropolyoxoanion precursors {[Ca(H2O)]6[P4M6O34]2}12− (M = WVI, MoVI) constructed by two [P4M6O34]12− subunits via a rare hexa-calcium cluster

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Article information


Submitted
12 Dec 2008
Accepted
11 Mar 2009
First published
27 Mar 2009

Chem. Commun., 2009, 2362-2364
Article type
Communication

A novel type of heteropolyoxoanion precursors {[Ca(H2O)]6[P4M6O34]2}12− (M = WVI, MoVI) constructed by two [P4M6O34]12− subunits via a rare hexa-calcium cluster

J. Wang, J. Zhao, P. Ma, J. Ma, L. Yang, Y. Bai, M. Li and J. Niu, Chem. Commun., 2009, 2362
DOI: 10.1039/B822368H

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