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Issue 11, 2009
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Bridgehead enolates and bridgeheadalkenes in a welwistatin model series

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Abstract

Bridgehead metallation is possible in a ketone having the welwistatin skeleton, and this facilitates installation of the isothiocyanate function present in the natural product, and also enables synthesis of remarkable bridgehead alkenes.

Graphical abstract: Bridgehead enolates and bridgeheadalkenes in a welwistatin model series

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Publication details

The article was received on 19 Nov 2008, accepted on 17 Dec 2008 and first published on 21 Jan 2009


Article type: Communication
DOI: 10.1039/B820674K
Chem. Commun., 2009, 1398-1400

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    Bridgehead enolates and bridgeheadalkenes in a welwistatin model series

    V. Boissel, N. S. Simpkins, G. Bhalay, A. J. Blake and W. Lewis, Chem. Commun., 2009, 1398
    DOI: 10.1039/B820674K

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