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Issue 17, 2009
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Ambiphilic allenes: synthesis and reactivity

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Abstract

Ambiphilic allenes are generated by an organocatalyzed domino reaction of alkyl propiolates and aromatic 1,2-diketones; in the absence of any external chemical agent, these allenes perform a thermally-driven dimerization reaction to generate the corresponding fully-substituted cyclobutanes in a regio- and highly stereoselective manner.

Graphical abstract: Ambiphilic allenes: synthesis and reactivity

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Article information


Submitted
04 Nov 2008
Accepted
06 Feb 2009
First published
11 Mar 2009

Chem. Commun., 2009, 2368-2370
Article type
Communication

Ambiphilic allenes: synthesis and reactivity

D. Tejedor, G. Méndez-Abt, J. González-Platas, M. A. Ramírez and F. García-Tellado, Chem. Commun., 2009, 2368
DOI: 10.1039/B819613C

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