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Issue 7, 2009
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A double intramolecular cage contraction within a self-assembled metallo-supramolecular bowl

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Abstract

When isolated in the high vacuum of an ESI-FTICR mass spectrometer, bowl-shaped metallo-supramolecular M6L4 assemblies undergo a surprising and mechanistically interesting intramolecular double cage contraction to yield smaller M3L2 cages.

Graphical abstract: A double intramolecular cage contraction within a self-assembled metallo-supramolecular bowl

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Article information


Submitted
31 Oct 2008
Accepted
10 Dec 2008
First published
14 Jan 2009

Chem. Commun., 2009, 785-787
Article type
Communication

A double intramolecular cage contraction within a self-assembled metallo-supramolecular bowl

B. Brusilowskij, S. Neubacher and C. A. Schalley, Chem. Commun., 2009, 785
DOI: 10.1039/B819412B

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