Issue 3, 2009
From the journal:

Chemical Communications

A novel approach for the design of a highly selective sulfate-ion-selective electrode†

Amarchand Sathyapalan,a   Anhong Zhou,*a   Tapas Kar,b   Feng Zhouc  and  Haibin Suc  

* Corresponding authors

a Department of Biological and Irrigation Engineering, Utah State University, Logan, Utah, USA
E-mail: Anhong.Zhou@usu.edu; a.sathyapalan@usu.edu
Fax: +1 (435)797-2863
Tel: +1 (435)797-2863

b Department of Chemistry, Utah State University, Logan, Utah, USA
E-mail: Tapas.Kar@usu.edu
Tel: (435)797-7230

c Division of Materials Science, Nanyang Technological University, 50 Nanyang Avenue, Singapore
E-mail: hbsu@ntu.edu.sg
Tel: +65 6790-4346

Abstract

A hydroxyl Schiff base molecule was synthesized from tetraethylenetetramine and 4-nitrosalicylaldehyde and explored as an ionophore with ionic liquid, cation excluder in PVC membranes showing remarkable sulfate selectivity; the optimal recognition site was predicted by density function theory (DFT) simulation.

Graphical abstract: A novel approach for the design of a highly selective sulfate-ion-selective electrode

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Article information

DOI
https://doi.org/10.1039/B817957C
Article type
Communication
Submitted
13 Oct 2008
Accepted
31 Oct 2008
First published
20 Nov 2008

Chem. Commun., 2009, 325-327

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A novel approach for the design of a highly selective sulfate-ion-selective electrode

A. Sathyapalan, A. Zhou, T. Kar, F. Zhou and H. Su, Chem. Commun., 2009, 325 DOI: 10.1039/B817957C

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