Issue 3, 2009
From the journal:

Chemical Communications

Shuffling lithiated mixed aggregates: NMR and Car–Parrinello molecular dynamics reveal an unexpected associative pathway†

Franck Paté,a   Hélène Gérard,b   Hassan Oulyadi,a   Aurélien de la Lande,b   Anne Harrison-Marchand,a   Olivier Pariselb  and  Jacques Maddaluno*a  

* Corresponding authors

a IRCOF, UMR CNRS 6014, Université et INSA de Rouen, Mont St Aignan Cedex, France

b UPMC Univ Paris 6 and CNRS, UMR 7616, Laboratoire de Chimie Théorique, 4 place Jussieu, Paris Cedex 05, France

Abstract

The exchange of Me6Li aggregated to a lithium amide by 7LiCl leads to a specific isotope distribution whose microscopic origin is assigned to an edge-to-edge interaction between the R2NLi–MeLi aggregate and (LiCl)2 by NMR and Car–Parrinello molecular dynamics.

Graphical abstract: Shuffling lithiated mixed aggregates: NMR and Car–Parrinello molecular dynamics reveal an unexpected associative pathway

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Article information

DOI
https://doi.org/10.1039/B814961E
Article type
Communication
Submitted
27 Aug 2008
Accepted
29 Oct 2008
First published
21 Nov 2008

Chem. Commun., 2009, 319-321

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Shuffling lithiated mixed aggregates: NMR and Car–Parrinello molecular dynamics reveal an unexpected associative pathway

F. Paté, H. Gérard, H. Oulyadi, A. de la Lande, A. Harrison-Marchand, O. Parisel and J. Maddaluno, Chem. Commun., 2009, 319 DOI: 10.1039/B814961E

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