Issue 6, 2009
From the journal:

Chemical Communications

High-valent manganese(v)–oxo porphyrin complexes in hydride transfer reactions†

Jung Yoon Lee,a   Yong-Min Lee,a   Hiroaki Kotani,b   Wonwoo Nam*a  and  Shunichi Fukuzumi*b  

* Corresponding authors

a Department of Chemistry and Nano Science, Centre for Biomimetic Systems, Ewha Womans University, Seoul, Korea
E-mail: wwnam@ewha.ac.kr
Fax: +82 2 3277 2392
Tel: +82 2 3277 4441

b Department of Material and Life Science, Graduate School of Engineering, Osaka University, SORST, Japan Science and Technology Agency (JST), Suita, Osaka, Japan
E-mail: fukuzumi@chem.eng.osaka-u.ac.jp
Fax: +81 6 6879 7370
Tel: +81 6 6879 7368

Abstract

Hydride transfer from dihydronicotinamide adenine dinucleotide (NADH) analogues to trans-dioxomanganese(V) porphyrin complexes proceeds viaproton-coupled electron transfer, followed by rapid electron transfer.

Graphical abstract: High-valent manganese(v)–oxo porphyrin complexes in hydride transfer reactions

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Article information

DOI
https://doi.org/10.1039/B814928C
Article type
Communication
Submitted
27 Aug 2008
Accepted
18 Nov 2008
First published
19 Dec 2008

Chem. Commun., 2009, 704-706

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High-valent manganese(V)–oxo porphyrin complexes in hydride transfer reactions

J. Y. Lee, Y. Lee, H. Kotani, W. Nam and S. Fukuzumi, Chem. Commun., 2009, 704 DOI: 10.1039/B814928C

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