Issue 1, 2009
From the journal:

Chemical Communications

Diazaphospholidine terminated polyhedral oligomeric silsesquioxanes in the hydroformylation of vinyl acetate†

Nicolas R. Vautraversa  and  David J. Cole-Hamilton*a  

* Corresponding authors

a EaStCHEM, School of Chemistry, University of St. Andrews, St. Andrews, Fife, UK
E-mail: djc@st-and.ac.uk
Fax: +44-1334-463808
Tel: +44-1334-463805

Abstract

The poorly active, monodentate SemiEsphos phosphine has been turned into an active ligand for rhodium catalysed vinyl acetate hydroformylation by attachment to the periphery of a polyhedral oligomeric silsesquioxane.

Graphical abstract: Diazaphospholidine terminated polyhedral oligomeric silsesquioxanes in the hydroformylation of vinyl acetate

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Article information

DOI
https://doi.org/10.1039/B814582B
Article type
Communication
Submitted
21 Aug 2008
Accepted
13 Oct 2008
First published
21 Nov 2008

Chem. Commun., 2009, 92-94

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Diazaphospholidine terminated polyhedral oligomeric silsesquioxanes in the hydroformylation of vinyl acetate

N. R. Vautravers and D. J. Cole-Hamilton, Chem. Commun., 2009, 92 DOI: 10.1039/B814582B

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