Issue 4, 2009
From the journal:

Chemical Communications

Tunable coordination of a troposphosphite for fine-tuning of the Rh catalyzed asymmetric addition of phenylboronic acid to cyclohexenone†

Anna Iuliano,*a   Sarah Facchettia  and  Tiziana Funaiolia  

* Corresponding authors

a Dipartimento di Chimica e Chimica Industriale Università di Pisa, Via Risorgimento 35, Pisa, Italy
E-mail: iuliano@dcci.unipi.it
Fax: +39 0502219260
Tel: +39 0502219231

Abstract

Using the deoxycholic acid derived tropos biphenylphosphite 1 as a Rh(I) chiralligand different complexes are obtained, depending on the Rh : L molar ratio, that give rise to the formation of different chiral products in the asymmetric addition of phenylboronic acid to cyclohexenone.

Graphical abstract: Tunable coordination of a troposphosphite for fine-tuning of the Rh catalyzed asymmetric addition of phenylboronic acid to cyclohexenone

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Article information

DOI
https://doi.org/10.1039/B814568G
Article type
Communication
Submitted
21 Aug 2008
Accepted
30 Oct 2008
First published
19 Nov 2008

Chem. Commun., 2009, 457-459

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Tunable coordination of a troposphosphite for fine-tuning of the Rh catalyzed asymmetric addition of phenylboronic acid to cyclohexenone

A. Iuliano, S. Facchetti and T. Funaioli, Chem. Commun., 2009, 457 DOI: 10.1039/B814568G

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