Issue 48, 2008
From the journal:

Chemical Communications

Dynamic structural conversion in a spin-crossover cobalt(ii) compound with long alkyl chains†

Shinya Hayami,*a   Kazuhisa Murata,a   Daisuke Urakami,a   Yoshihiro Kojima,a   Motoko Akitaa  and  Katsuya Inoueab  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, Japan
E-mail: hayami@hiroshima-u.ac.jp
Fax: 8182424 7418
Tel: 81 82 424 7418

b Institute for Advanced Material Research, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, Japan

Abstract

A cobalt(II) compound [Co(C14-terpy)2](BF4)2·MeOH (1) with long alkyl chains was prepared, and exhibited unique SCO at T1 = 50 K and spin transition at T2↑ = 206 K and T2↓ = 184 K with hysteresis (ΔT = 22 K) accompanying the motion of the long alkyl chains.

Graphical abstract: Dynamic structural conversion in a spin-crossover cobalt(ii) compound with long alkyl chains

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Article information

DOI
https://doi.org/10.1039/B814415J
Article type
Communication
Submitted
19 Aug 2008
Accepted
30 Sep 2008
First published
04 Nov 2008

Chem. Commun., 2008, 6510-6512

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Dynamic structural conversion in a spin-crossover cobalt(II) compound with long alkyl chains

S. Hayami, K. Murata, D. Urakami, Y. Kojima, M. Akita and K. Inoue, Chem. Commun., 2008, 6510 DOI: 10.1039/B814415J

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