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Issue 46, 2008

Enhancement of H2adsorption in Li+-exchanged co-ordination framework materials

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Abstract

H2 adsorption in (Me2NH2)[In(L)] is enhanced by exchange of Me2NH2+ for Li+ cations; the Li+-exchanged material displays a lower isosteric heat for H2 adsorption than the parent material, indicating that the increase in H2 capacity is due to an increase in the accessible pore volume on cation exchange, while the lower adsorption enthalpy is consistent with increased pore size.

Graphical abstract: Enhancement of H2 adsorption in Li+-exchanged co-ordination framework materials

Supplementary files

Article information


Submitted
14 Aug 2008
Accepted
25 Sep 2008
First published
14 Oct 2008

Chem. Commun., 2008, 6108-6110
Article type
Communication

Enhancement of H2 adsorption in Li+-exchanged co-ordination framework materials

S. Yang, X. Lin, A. J. Blake, K. M. Thomas, P. Hubberstey, N. R. Champness and M. Schröder, Chem. Commun., 2008, 6108 DOI: 10.1039/B814155J

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