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Issue 42, 2008
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Rhodium-catalysed cyclisation reaction of allenynes with arylboronic acids

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Abstract

Allenynes having malonate-based tethers reacted with arylboronic acids in the presence of a rhodium(I) catalyst to sequentially form three carbon–carbon bonds, and arylated bicyclic skeletons were constructed in a stereoselective manner.

Graphical abstract: Rhodium-catalysed cyclisation reaction of allenynes with arylboronic acids

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Publication details

The article was received on 24 Jun 2008, accepted on 22 Jul 2008 and first published on 16 Sep 2008


Article type: Communication
DOI: 10.1039/B810665G
Chem. Commun., 2008, 5366-5368

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    Rhodium-catalysed cyclisation reaction of allenynes with arylboronic acids

    T. Miura, K. Ueda, Y. Takahashi and M. Murakami, Chem. Commun., 2008, 5366
    DOI: 10.1039/B810665G

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