Issue 40, 2008
From the journal:

Chemical Communications

Drastic effect of bidentate phosphine ligands on Pd-catalyzed hydroarylation of ethyl propiolate: a simple route to arylbutadienes†

Juzo Oyamadaa  and  Tsugio Kitamura*a  

* Corresponding authors

a Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University, 1 Honjo-machi, Saga, Japan
E-mail: kitamura@cc.saga-u.ac.jp
Fax: 81-952-28-8548
Tel: 81-952-28-8550

Abstract

Palladium complexes with bidentate phosphine ligands, Pd(dppe)(OAc)2 and Pd(dppm)(OAc)2, were found to be effective catalysts for reactions of simple arenes with ethyl propiolate, affording arylbutadiene derivatives selectively.

Graphical abstract: Drastic effect of bidentate phosphine ligands on Pd-catalyzed hydroarylation of ethyl propiolate: a simple route to arylbutadienes

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Article information

DOI
https://doi.org/10.1039/B810658D
Article type
Communication
Submitted
24 Jun 2008
Accepted
21 Jul 2008
First published
12 Sep 2008

Chem. Commun., 2008, 4992-4994

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Drastic effect of bidentate phosphine ligands on Pd-catalyzed hydroarylation of ethyl propiolate: a simple route to arylbutadienes

J. Oyamada and T. Kitamura, Chem. Commun., 2008, 4992 DOI: 10.1039/B810658D

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