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Issue 41, 2008
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Separation of a diiminopyridine iron(II) complex into rac- and meso- diastereoisomers provides evidence for a dual stereoregulation mechanism in propenepolymerization

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Abstract

Separation of a diiminopyridine iron(II) complex into its rac- and meso- diastereoisomers provides for first time the opportunity of observing the enantiomorphic site control competing with the chain-end control mechanism in a non-metallocene catalyst system.

Graphical abstract: Separation of a diiminopyridine iron(ii) complex into rac- and meso- diastereoisomers provides evidence for a dual stereoregulation mechanism in propenepolymerization

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Publication details

The article was received on 18 Jun 2008, accepted on 13 Aug 2008 and first published on 12 Sep 2008


Article type: Communication
DOI: 10.1039/B810381J
Citation: Chem. Commun., 2008,0, 5230-5232

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    Separation of a diiminopyridine iron(II) complex into rac- and meso- diastereoisomers provides evidence for a dual stereoregulation mechanism in propenepolymerization

    A. Rodríguez-Delgado, J. Cámpora, A. M. Naz, P. Palma and M. L. Reyes, Chem. Commun., 2008, 0, 5230
    DOI: 10.1039/B810381J

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