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Issue 39, 2008
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Selected regiocontrolled transformations applied to the synthesis of (1S)-cis-chrysanthemic acid from (1S)-3,4-epoxy-2,2,5,5-tetramethylcyclohexanol

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Abstract

(1S)-cis-Chrysanthemic acid has been prepared in a few steps with complete control of the relative and absolute stereochemistry using regiocontrolled epoxide ring opening, diol mono-oxidation and cyclopropanation.

Graphical abstract: Selected regiocontrolled transformations applied to the synthesis of (1S)-cis-chrysanthemic acid from (1S)-3,4-epoxy-2,2,5,5-tetramethylcyclohexanol

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Article information


Submitted
22 May 2008
Accepted
10 Jul 2008
First published
26 Aug 2008

Chem. Commun., 2008, 4753-4755
Article type
Communication

Selected regiocontrolled transformations applied to the synthesis of (1S)-cis-chrysanthemic acid from (1S)-3,4-epoxy-2,2,5,5-tetramethylcyclohexanol

A. Krief, H. Y. Gondal and A. Kremer, Chem. Commun., 2008, 4753
DOI: 10.1039/B808695H

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