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Issue 41, 2008
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Enantiomerically purebicyclo[3.3.1]nona-2,6-diene as the sole source of enantioselectivity in BIPHEP-Rh asymmetric hydrogenation

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Abstract

In situ resolution of the rapidly racemising diphosphine BIPHEP and its relatives with the cationic Rh complex of (S,S)-bicyclonona-2,6-diene permits the asymmetric hydrogenation of dehydroamino esters.

Graphical abstract: Enantiomerically pure bicyclo[3.3.1]nona-2,6-diene as the sole source of enantioselectivity in BIPHEP-Rh asymmetric hydrogenation

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Article information


Submitted
06 May 2008
Accepted
13 Aug 2008
First published
12 Sep 2008

Chem. Commun., 2008, 5092-5094
Article type
Communication

Enantiomerically pure bicyclo[3.3.1]nona-2,6-diene as the sole source of enantioselectivity in BIPHEP-Rh asymmetric hydrogenation

T. Punniyamurthy, M. Mayr, A. S. Dorofeev, C. J. R. Bataille, S. Gosiewska, B. Nguyen, A. R. Cowley and J. M. Brown, Chem. Commun., 2008, 5092
DOI: 10.1039/B807669C

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