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Issue 39, 2008
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Microporous vanadyl-arsenate with the template incorporated exhibiting sorption and catalytic properties†

Teresa Berrocal,a   José L. Mesa,*b   José L. Pizarro,a   Begoña Bazán,a   Marta Iglesias,c   Andrés T. Aguayo,d   María I. Arriortuaa  and  Teófilo Rojo*b  
Author affiliations

* Corresponding authors

a Dpto. de Mineralogía y Petrología, Facultad de Ciencia y Tecnología, Universidad del País Vasco, Apdo. 644, Bilbao, Spain

b Dpto. de Química Inorgánica, Facultad de Ciencia y Tecnología, Universidad del País Vasco, Apdo. 644, Bilbao, Spain
E-mail: joseluis.mesa@ehu.es

c Instituto de Ciencia de Materiales de Madrid, CSIC, C/ Sor Juana Inés de la Cruz 3, Cantoblanco, Madrid, Spain

d Dpto. de Ingeniería Química, Facultad de Ciencia y Tecnología, Universidad del País Vasco, Apdo. 64, Bilbao, Spain

Abstract

(C5H14N2)[(VO)3(AsO4)(HAsO4)2(OH)]·3H2O behaves as a microporous organically templated compound, with reversible adsorption and desorption of N2 at 77 K, and as an extremely efficient catalyst that catalyzes selective sulfoxide formation from organic sulfides, under mild conditions.

Graphical abstract: Microporous vanadyl-arsenate with the template incorporated exhibiting sorption and catalytic properties

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Article information

https://doi.org/10.1039/B807250G
Submitted
29 Apr 2008
Accepted
25 Jul 2008
First published
05 Sep 2008
Chem. Commun., 2008, 4738-4740
Article type
Communication
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Microporous vanadyl-arsenate with the template incorporated exhibiting sorption and catalytic properties

T. Berrocal, J. L. Mesa, J. L. Pizarro, B. Bazán, M. Iglesias, A. T. Aguayo, M. I. Arriortua and T. Rojo, Chem. Commun., 2008, 4738
DOI: 10.1039/B807250G

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