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Issue 26, 2008
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Ammonium salts as an inexpensive and convenient nitrogen source in the Cu-catalyzed amination of aryl halides at room temperature

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Abstract

Convenient and inexpensive ammonium salts such as NH4Cl and aqueous NH3 solution are found to be readily utilized in the Cu-catalyzed room temperature N-arylation of aryl halides, providing N-unprotected aniline derivatives in high yields.

Graphical abstract: Ammonium salts as an inexpensive and convenient nitrogen source in the Cu-catalyzed amination of aryl halides at room temperature

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Article information


Submitted
18 Mar 2008
Accepted
30 Mar 2008
First published
23 May 2008

Chem. Commun., 2008, 3052-3054
Article type
Communication

Ammonium salts as an inexpensive and convenient nitrogen source in the Cu-catalyzed amination of aryl halides at room temperature

J. Kim and S. Chang, Chem. Commun., 2008, 3052
DOI: 10.1039/B804637A

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