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Issue 22, 2008

Fast stereoselective reactions in electrosprayed Co(ii)/neurotransmitter nanodroplets

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Abstract

Collision induced dissociation (CID) of the m/z 479 ion, formed by ESI of Co(NO3)2–CH3OH solutions with either pure (1S,2S)-(+)-N-methylpseudoephedrine or its mixtures with (1S,2R)-(+)- or (1R,2S)-(−)-ephedrine, provides compelling evidence for fast, stereoselective reactions in Co(II)/neurotrasmitter(s) aggregates during solvent evaporation of the ESI droplets.

Graphical abstract: Fast stereoselective reactions in electrosprayed Co(ii)/neurotransmitter nanodroplets

Supplementary files

Article information


Submitted
22 Jan 2008
Accepted
05 Mar 2008
First published
04 Apr 2008

Chem. Commun., 2008, 2544-2546
Article type
Communication

Fast stereoselective reactions in electrosprayed Co(II)/neurotransmitter nanodroplets

C. Fraschetti, M. Aschi, A. Filippi, A. Giardini and M. Speranza, Chem. Commun., 2008, 2544 DOI: 10.1039/B801201F

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