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Issue 18, 2008
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Construction of C1-symmetric zirconium complexes by the design of new Salan ligands. Coordination chemistry and preliminary polymerisation catalysis studies

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Abstract

The first synthesis of achiral and chiral [ONNO′]-type Salan ligands featuring two different phenol arms, and the diastereoselective formation of the corresponding octahedral C1-symmetric zirconium complexes is described; the activity and isospecificity induction of the [ONNO′]Zr(bn)2 complexes in 1-hexene polymerisation reflected those of the parent symmetric compounds.

Graphical abstract: Construction of C1-symmetric zirconium complexes by the design of new Salan ligands. Coordination chemistry and preliminary polymerisation catalysis studies

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Publication details

The article was received on 02 Jan 2008, accepted on 14 Feb 2008 and first published on 04 Mar 2008


Article type: Communication
DOI: 10.1039/B719834E
Chem. Commun., 2008, 2149-2151

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    Construction of C1-symmetric zirconium complexes by the design of new Salan ligands. Coordination chemistry and preliminary polymerisation catalysis studies

    A. Cohen, A. Yeori, J. Kopilov, I. Goldberg and M. Kol, Chem. Commun., 2008, 2149
    DOI: 10.1039/B719834E

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