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Issue 20, 2008
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Direct synthesis of bicyclic guanidines through unprecedented palladium(II) catalysed diamination with copper chloride as oxidant

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Abstract

Palladium catalysed intramolecular guanidine transfer to alkenes can be accomplished with copper chloride as the oxidant to give bicyclic guanidines with complete selectivity and in high yields.

Graphical abstract: Direct synthesis of bicyclic guanidines through unprecedented palladium(ii) catalysed diamination with copper chloride as oxidant

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Publication details

The article was received on 19 Dec 2007, accepted on 11 Feb 2008 and first published on 14 Mar 2008


Article type: Communication
DOI: 10.1039/B719479J
Chem. Commun., 2008, 2334-2336

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    Direct synthesis of bicyclic guanidines through unprecedented palladium(II) catalysed diamination with copper chloride as oxidant

    C. H. Hövelmann, J. Streuff, L. Brelot and K. Muñiz, Chem. Commun., 2008, 2334
    DOI: 10.1039/B719479J

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