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Issue 14, 2008
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Asymmetric oxidation of sulfides under solvent-free or highly concentrated conditions

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Abstract

The aluminium(salalen) complex was found to be an efficient catalyst for the asymmetric oxidation of sulfides under solvent-free or highly concentrated conditions, in which an only 0.002–0.01 mol% catalyst loading was sufficient to obtain optically active sulfoxides in high yield with high enantioselectivity.

Graphical abstract: Asymmetric oxidation of sulfides under solvent-free or highly concentrated conditions

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Article information


Submitted
14 Dec 2007
Accepted
29 Jan 2008
First published
05 Feb 2008

Chem. Commun., 2008, 1704-1706
Article type
Communication

Asymmetric oxidation of sulfides under solvent-free or highly concentrated conditions

K. Matsumoto, T. Yamaguchi and T. Katsuki, Chem. Commun., 2008, 1704
DOI: 10.1039/B719265G

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