Issue 12, 2008
From the journal:

Chemical Communications

Direct C–H bond arylation of arenes with aryltin reagents catalysed by palladium complexes†

Hiroshi Kawai,a   Yasuhiro Kobayashi,a   Shuichi Oi*a  and  Yoshio Inoue*a  

* Corresponding authors

a Department of Biomolecular Engineering, Graduate School of Engineering, Tohoku University, Sendai 980-8579, Japan
E-mail: oishu@aporg.che.tohoku.ac.jp
Fax: +81 (0)22 795 5876
Tel: +81 (0)22 795 5876

Abstract

Direct C–H bond arylation of simple arenes with aryltin reagents has been successfully catalysed by PdCl2 in the presence of CuCl2. CuCl2 proved to be an activator for a palladium intermediate as well as an oxidant.

Graphical abstract: Direct C–H bond arylation of arenes with aryltin reagents catalysed by palladium complexes

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Article information

DOI
https://doi.org/10.1039/B717251F
Article type
Communication
Submitted
07 Nov 2007
Accepted
19 Dec 2007
First published
29 Jan 2008

Chem. Commun., 2008, 1464-1466

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Direct C–H bond arylation of arenes with aryltin reagents catalysed by palladium complexes

H. Kawai, Y. Kobayashi, S. Oi and Y. Inoue, Chem. Commun., 2008, 1464 DOI: 10.1039/B717251F

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