Issue 17, 2008
From the journal:

Chemical Communications

Identification of an intermediate in the deboronation of ortho-carborane: an adduct of ortho-carborane with two nucleophiles on one boron atom†‡

Yoshiyuki Taoda,a   Takehiko Sawabe,a   Yasuyuki Endo,*b   Kentaro Yamaguchi,c   Shinya Fujiid  and  Hiroyuki Kagechika*d  

* Corresponding authors

a Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Japan

b Tohoku Pharmaceutical University, 4-4-1 Komatsushima, Aoba-ku, Japan
E-mail: yendo@tohoku-pharm.ac.jp
Fax: +81 22-275-2013

c Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, 1314-1 Shido, Sanuki, Japan

d School of Biomedical Science, Institute of Biomaterials and Bioengineering, Tokyo Medical and Dental University, 2-3-10 Kanda-Surugadai, Chiyoda-ku, Japan
E-mail: kage.omc@tmd.ac.jp
Fax: +81 3-5280-8032

Abstract

The 1 : 2 adduct of 1-bromo-ortho-carborane and pyridine has been identified as a significant intermediate in the deboronation of ortho-carborane to a nido-anion

Graphical abstract: Identification of an intermediate in the deboronation of ortho-carborane: an adduct of ortho-carborane with two nucleophiles on one boron atom

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Article information

DOI
https://doi.org/10.1039/B716079H
Article type
Communication
Submitted
17 Oct 2007
Accepted
29 Jan 2008
First published
20 Feb 2008

Chem. Commun., 2008, 2049-2051

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Identification of an intermediate in the deboronation of ortho-carborane: an adduct of ortho-carborane with two nucleophiles on one boron atom

Y. Taoda, T. Sawabe, Y. Endo, K. Yamaguchi, S. Fujii and H. Kagechika, Chem. Commun., 2008, 2049 DOI: 10.1039/B716079H

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