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Issue 9, 2008
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Unprecedented twofold intramolecular hydroamination in diam(m)ine-dicarboxylatodichloridoplatinum(IV) complexes – ethane-1,2-diaminevs.ammine ligands

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Abstract

Reaction of (OC-6-13)-bis(2Z-3-carboxyacrylato)dichlorido(ethane-1,2-diamine)platinum(IV) and (OC-6-13)-diamminebis(2Z-3-carboxyacrylato)dichloridoplatinum(IV) with propylamine in the presence of 1,1′-carbonyl diimidazole afforded not the expected amides; instead, beside amide formation, a twofold intramolecular attack of the am(m)ine ligand at the C[double bond, length as m-dash]C bonds was observed involving either both (ethane-1,2-diamine) or only one (ammine) coordinated nitrogen atom(s).

Graphical abstract: Unprecedented twofold intramolecular hydroamination in diam(m)ine-dicarboxylatodichloridoplatinum(iv) complexes – ethane-1,2-diaminevs.ammine ligands

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Publication details

The article was received on 11 Oct 2007, accepted on 14 Dec 2007 and first published on 09 Jan 2008


Article type: Communication
DOI: 10.1039/B715680D
Citation: Chem. Commun., 2008,0, 1091-1093

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    Unprecedented twofold intramolecular hydroamination in diam(m)ine-dicarboxylatodichloridoplatinum(IV) complexes – ethane-1,2-diaminevs.ammine ligands

    M. R. Reithofer, M. Galanski, V. B. Arion and B. K. Keppler, Chem. Commun., 2008, 0, 1091
    DOI: 10.1039/B715680D

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