Issue 3, 2008
From the journal:

Chemical Communications

A coincident spontaneous resolution system for racemic1,1′-binaphthyl-2,2′-dicarboxylic acid and 1,2-diphenylethylenediamine induced by water†

Yoshitane Imai,*a   Kakuhiro Kawaguchi,a   Nobuo Tajima,b   Tomohiro Sato,c   Reiko Kurodacd  and  Yoshio Matsubara*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka, Japan
E-mail: y-imai@apch.kindai.ac.jp, y-matsu@apch.kindai.ac.jp

b First-Principles Simulation Group, Computational Materials Science Center, NIMS, Sengen, Tsukuba, Ibaraki, Japan

c JST ERATO-SORST Kuroda Chiromorphology Team, 4-7-6 Komaba, Meguro-ku, Tokyo, Japan

d Department of Life Sciences, Graduate School of Arts and Sciences, The University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo, Japan

Abstract

Spontaneously resolvable conglomerate crystals are obtained by combining racemic(rac)-1,1′-binaphthyl-2,2′-dicarboxylic acid and rac-1,2-diphenylethylenediamine, and this spontaneous resolution system is induced by water which is present in the crystallization solvent.

Graphical abstract: A coincident spontaneous resolution system for racemic1,1′-binaphthyl-2,2′-dicarboxylic acid and 1,2-diphenylethylenediamine induced by water

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Article information

DOI
https://doi.org/10.1039/B714226A
Article type
Communication
Submitted
14 Sep 2007
Accepted
05 Nov 2007
First published
09 Nov 2007

Chem. Commun., 2008, 362-364

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A coincident spontaneous resolution system for racemic1,1′-binaphthyl-2,2′-dicarboxylic acid and 1,2-diphenylethylenediamine induced by water

Y. Imai, K. Kawaguchi, N. Tajima, T. Sato, R. Kuroda and Y. Matsubara, Chem. Commun., 2008, 362 DOI: 10.1039/B714226A

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