Issue 1, 2008
From the journal:

Chemical Communications

Rh-catalyzed P–P bond activation†

Stephen J. Geiera  and  Douglas W. Stephan*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Windsor, Windsor, Ontario, Canada
E-mail: Stephan@uwindsor.ca
Fax: +1 519-973-7098

Abstract

A Rh-catalyst derived from (NacNac)Rh(COE)(N2) effects the hydrogenation and silylation of P–P bonds to give secondary phosphines and silylphosphines, (Ph2PH) and (Ph2PSiRR′2) respectively; the latter process is shown to also involve the silylation of secondary phosphines.

Graphical abstract: Rh-catalyzed P–P bond activation

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Article information

DOI
https://doi.org/10.1039/B712972F
Article type
Communication
Submitted
23 Aug 2007
Accepted
28 Sep 2007
First published
16 Oct 2007

Chem. Commun., 2008, 99-101

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Rh-catalyzed P–P bond activation

S. J. Geier and D. W. Stephan, Chem. Commun., 2008, 99 DOI: 10.1039/B712972F

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