Issue 2, 2008

Crabtree's catalyst revisited; Ligand effects on stability and durability

Abstract

The extent of time-dependent deactivation of monophosphine monoamine iridium hydrogenation catalysts by trimer formation is strongly dependent on ligand structure; attempts to counter this process lead to the observation of an oligomerisation resistant catalyst.

Graphical abstract: Crabtree's catalyst revisited; Ligand effects on stability and durability

Supplementary files

Article information

Article type
Communication
Submitted
03 Aug 2007
Accepted
24 Sep 2007
First published
18 Oct 2007

Chem. Commun., 2008, 199-201

Crabtree's catalyst revisited; Ligand effects on stability and durability

Y. Xu, D. M. P. Mingos and J. M. Brown, Chem. Commun., 2008, 199 DOI: 10.1039/B711979H

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