Jump to main content
Jump to site search

Issue 42, 2007
Previous Article Next Article

On the structure of a proposed mixed-valent analogue of the diiron subsite of [FeFe]-hydrogenase

Author affiliations

Abstract

We show that a dinuclear assembly apparently providing the first example of a synthetic molecule exhibiting key features of the diiron subsite of [FeFe] hydrogenase, viz. CO-bridging of a coordinatively unsaturated, dithiolate-bridged mixed-valence diiron centre, is in fact a diamagnetic tetranuclear complex.

Graphical abstract: On the structure of a proposed mixed-valent analogue of the diiron subsite of [FeFe]-hydrogenase

Back to tab navigation

Supplementary files

Publication details

The article was received on 23 Aug 2007, accepted on 14 Sep 2007 and first published on 01 Oct 2007


Article type: Communication
DOI: 10.1039/B712758H
Citation: Chem. Commun., 2007,0, 4348-4350

  •   Request permissions

    On the structure of a proposed mixed-valent analogue of the diiron subsite of [FeFe]-hydrogenase

    S. P. Best, S. J. Borg, J. M. White, M. Razavet and C. J. Pickett, Chem. Commun., 2007, 0, 4348
    DOI: 10.1039/B712758H

Search articles by author

Spotlight

Advertisements