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Issue 42, 2007
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On the structure of a proposed mixed-valent analogue of the diiron subsite of [FeFe]-hydrogenase

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Abstract

We show that a dinuclear assembly apparently providing the first example of a synthetic molecule exhibiting key features of the diiron subsite of [FeFe] hydrogenase, viz. CO-bridging of a coordinatively unsaturated, dithiolate-bridged mixed-valence diiron centre, is in fact a diamagnetic tetranuclear complex.

Graphical abstract: On the structure of a proposed mixed-valent analogue of the diiron subsite of [FeFe]-hydrogenase

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Supplementary files

Article information


Submitted
23 Aug 2007
Accepted
14 Sep 2007
First published
01 Oct 2007

Chem. Commun., 2007, 4348-4350
Article type
Communication

On the structure of a proposed mixed-valent analogue of the diiron subsite of [FeFe]-hydrogenase

S. P. Best, S. J. Borg, J. M. White, M. Razavet and C. J. Pickett, Chem. Commun., 2007, 4348
DOI: 10.1039/B712758H

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