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Issue 46, 2007
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Catalytically efficient palladium nanoparticles stabilized by “click” ferrocenyl dendrimers

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Abstract

1,2,3-Ferrocenyl triazole ligands generated by click reactions in dendrimers bind Pd(OAc)2 with a systematic one-to-one stoichiometry as monitored by titration using the ferrocenyl redox sensor attached to the triazole ring, and the dendritic PdII complexes formed are best reduced by methanol to form palladium nanoparticles of designed types and sizes that show excellent efficiency and selectivity in olefin hydrogenation.

Graphical abstract: Catalytically efficient palladium nanoparticles stabilized by “click” ferrocenyl dendrimers

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Publication details

The article was received on 17 Jul 2007, accepted on 06 Sep 2007 and first published on 20 Sep 2007


Article type: Communication
DOI: 10.1039/B710925C
Chem. Commun., 2007, 4946-4948

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    Catalytically efficient palladium nanoparticles stabilized by “click” ferrocenyl dendrimers

    C. Ornelas, L. Salmon, J. Ruiz Aranzaes and D. Astruc, Chem. Commun., 2007, 4946
    DOI: 10.1039/B710925C

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