Issue 44, 2007
From the journal:

Chemical Communications

Cobalt-catalyzed intermolecular C–H amination with bromamine-T as nitrene source†

Jeremiah D. Harden,a   Joshua V. Ruppel,a   Guang-Yao Gaoa  and  X. Peter Zhang*a  

* Corresponding authors

a Department of Chemistry, University of South Florida, Knoxville, USA, USA
E-mail: pzhang@cas.usf.edu
Fax: +1 813 974 7249
Tel: +1 813 974 1733

Abstract

Cobalt, supported by porphyrin ligands, is capable of catalyzing intermolecular nitrene insertion of sp3 C–H bonds with bromamine-T as the nitrene source, forming the desired tosyl-protected amines with NaBr as the by-product.

Graphical abstract: Cobalt-catalyzed intermolecular C–H amination with bromamine-T as nitrene source

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B710677G
Article type
Communication
Submitted
12 Jul 2007
Accepted
22 Aug 2007
First published
03 Sep 2007

Chem. Commun., 2007, 4644-4646

Permissions

Request permissions

Cobalt-catalyzed intermolecular C–H amination with bromamine-T as nitrene source

J. D. Harden, J. V. Ruppel, G. Gao and X. P. Zhang, Chem. Commun., 2007, 4644 DOI: 10.1039/B710677G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements