Issue 40, 2007
From the journal:

Chemical Communications

Iterative approach to polyketide-type structures: stereoselective synthesis of 1,3-polyols utilizing the catalytic asymmetric Overman esterification†

Jörg T. Bindera  and  Stefan F. Kirsch*a  

* Corresponding authors

a Department Chemie, Technische Universität München, Lichtenbergstr. 4, Garching, Germany
E-mail: stefan.kirsch@ch.tum.de
Fax: (+49) 89-2891-3315

Abstract

An iterative systematic approach to the 1,3-polyol motif has been developed to provide access to all possible stereoisomers by utilizing the catalytic asymmetric Overman esterification for the construction of all stereogenic centres.

Graphical abstract: Iterative approach to polyketide-type structures: stereoselective synthesis of 1,3-polyols utilizing the catalytic asymmetric Overman esterification

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Article information

DOI
https://doi.org/10.1039/B708248G
Article type
Communication
Submitted
31 May 2007
Accepted
19 Jul 2007
First published
06 Aug 2007

Chem. Commun., 2007, 4164-4166

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Iterative approach to polyketide-type structures: stereoselective synthesis of 1,3-polyols utilizing the catalytic asymmetric Overman esterification

J. T. Binder and S. F. Kirsch, Chem. Commun., 2007, 4164 DOI: 10.1039/B708248G

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