Issue 31, 2007

Rhodium(i)-catalysed conjugate phosphination of cyclic α,β-unsaturated ketones with silylphosphines as masked phosphinides

Abstract

Nucleophile-activation of the phosphorus(III)–silicon linkage in silylphosphines generates a nucleophilic phosphorus(III) equivalent thereby allowing for a rhodium-catalysed conjugate phosphination of β-substituted α,β-unsaturated acceptors.

Graphical abstract: Rhodium(i)-catalysed conjugate phosphination of cyclic α,β-unsaturated ketones with silylphosphines as masked phosphinides

Supplementary files

Article information

Article type
Communication
Submitted
24 Apr 2007
Accepted
22 May 2007
First published
11 Jun 2007

Chem. Commun., 2007, 3300-3302

Rhodium(I)-catalysed conjugate phosphination of cyclic α,β-unsaturated ketones with silylphosphines as masked phosphinides

V. T. Trepohl and M. Oestreich, Chem. Commun., 2007, 3300 DOI: 10.1039/B706137D

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