Issue 32, 2007
From the journal:

Chemical Communications

Halogen-bonded assembly of hybrid inorganic/organic 3D-networks from dibromocuprate salts and tetrabromomethane†

Sergiy V. Rosokha,a   Jianjiang Lu,a   Tetyana Y. Rosokhaa  and  Jay K. Kochi*a  

* Corresponding authors

a Department of Chemistry, University of Houston, Houston, TX, USA
E-mail: jkochi@uh.edu
Fax: 713-743-2709
Tel: 713-743-3293

Abstract

The critical halogen-bonding motif (CBr⋯BrCu) is responsible for the successful synthesis of three-dimensional networks of unusual 4,5-connected dodecahedron cells (each containing the encapsulated cation) via the self-assembly of tetra-n-propylammonium dibromocuprate(I) and tetrabromomethane as prototypical donor/acceptor dyads.

Graphical abstract: Halogen-bonded assembly of hybrid inorganic/organic 3D-networks from dibromocuprate salts and tetrabromomethane

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Article information

DOI
https://doi.org/10.1039/B705882A
Article type
Communication
Submitted
17 Apr 2007
Accepted
18 May 2007
First published
18 Jun 2007

Chem. Commun., 2007, 3383-3385

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Halogen-bonded assembly of hybrid inorganic/organic 3D-networks from dibromocuprate salts and tetrabromomethane

S. V. Rosokha, J. Lu, T. Y. Rosokha and J. K. Kochi, Chem. Commun., 2007, 3383 DOI: 10.1039/B705882A

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