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Issue 31, 2007
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One-step assembly of a chiral palladium bis(acyclic diaminocarbene) complex and its unexpected oxidation to a bis(amidine) complex

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Abstract

Addition of trans-N,N′-dimethyl-1,2-diaminocyclohexane to a palladium bis(arylisocyanide) complex leads to the one-step formation of the first chiral bis(acyclic diaminocarbene) complex, which is thermally stable under N2 but undergoes slow oxidation to a bis(amidine) complex under air.

Graphical abstract: One-step assembly of a chiral palladium bis(acyclic diaminocarbene) complex and its unexpected oxidation to a bis(amidine) complex

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Publication details

The article was received on 13 Mar 2007, accepted on 22 May 2007 and first published on 11 Jun 2007


Article type: Communication
DOI: 10.1039/B703769D
Chem. Commun., 2007, 3294-3296

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    One-step assembly of a chiral palladium bis(acyclic diaminocarbene) complex and its unexpected oxidation to a bis(amidine) complex

    Y. A. Wanniarachchi and L. M. Slaughter, Chem. Commun., 2007, 3294
    DOI: 10.1039/B703769D

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