Issue 28, 2007

Chirality induction in a cation-driven assembly using a crowned metalloporphyrin

Abstract

15-Crown-5-appended metalloporphyrin causes a K+-driven self-organization to bind a bifunctional guest ditopically, thereby allowing the circular dichroism (CD) detection of chirality induced in the ensemble when chiral amines are employed as the guest; the chiroptical properties are discussed.

Graphical abstract: Chirality induction in a cation-driven assembly using a crowned metalloporphyrin

Supplementary files

Article information

Article type
Communication
Submitted
12 Mar 2007
Accepted
24 Apr 2007
First published
17 May 2007

Chem. Commun., 2007, 2953-2955

Chirality induction in a cation-driven assembly using a crowned metalloporphyrin

Y. Ishii, Y. Soeda and Y. Kubo, Chem. Commun., 2007, 2953 DOI: 10.1039/B703670A

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