Issue 26, 2007
From the journal:

Chemical Communications

Singly-bonded fullerene dimers: neutral (C60Cl5)2 and cationic (C70)22+ †

Sergey I. Troyanov*a  and  Erhard Kemnitz*b  

* Corresponding authors

a Department of Chemistry, Moscow State University, Moscow, Russia
E-mail: stroyano@thermo.chem.msu.ru
Fax: +7 495 9391240
Tel: +7 495 9395396

b Institute of Chemistry, Humboldt University, Berlin, Germany
E-mail: erhard.kemnitz@chemie.hu-berlin.de
Fax: +49 30 20937277
Tel: +49 30 20937555

Abstract

C60Br24 and C70Br10 react with TiCl4, splitting out bromine, and, after Br/Cl exchange, forming singly-bonded dimeric structures (C60Cl5)2 and [(C70)2](Ti3Cl13)2, respectively, the latter consisting of dimeric [(C70)2]2+ dications and (Ti3Cl13)− anions.

Graphical abstract: Singly-bonded fullerene dimers: neutral (C60Cl5)2 and cationic (C70)22+

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B702665J
Article type
Communication
Submitted
21 Feb 2007
Accepted
28 Mar 2007
First published
19 Apr 2007

Chem. Commun., 2007, 2707-2709

Permissions

Request permissions

Singly-bonded fullerene dimers: neutral (C60Cl5)2 and cationic (C70)22+

S. I. Troyanov and E. Kemnitz, Chem. Commun., 2007, 2707 DOI: 10.1039/B702665J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements