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Issue 17, 2007
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Aryl bromide/triflate selectivities reveal mechanistic divergence in palladium-catalysed couplings; the Suzuki–Miyaura anomaly

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Abstract

In palladium-catalysed cross-coupling reactions, the outcome of competition between aryl bromides and aryl triflates depends on the nucleophilic partner; Suzuki couplings with R–B generally follow a different pattern from other R–M species.

Graphical abstract: Aryl bromide/triflate selectivities reveal mechanistic divergence in palladium-catalysed couplings; the Suzuki–Miyaura anomaly

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Article information


Submitted
31 Jan 2007
Accepted
26 Mar 2007
First published
05 Apr 2007

Chem. Commun., 2007, 1742-1744
Article type
Communication

Aryl bromide/triflate selectivities reveal mechanistic divergence in palladium-catalysed couplings; the Suzuki–Miyaura anomaly

G. Espino, A. Kurbangalieva and J. M. Brown, Chem. Commun., 2007, 1742
DOI: 10.1039/B701517H

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